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Message: Re: Methane to Methanol - Holy Grail of Catalysis

I did not mention it...but I thought something similar myself.  Great minds must think alike...thanks for the input Janneman.

For HPQ, I wonder if they are using something like Gallium (a byproduct of zinc smelting I think) as I read an article about the copious amounts of hyrogen that you can derive from Gallium.  Perhaps they use some sort of catalyst to jump start the electrolysis process - which is why perhaps only low levels of electricity are required.   The EBH2 referenced "room tempature" as a requirement in their presentation.  Gallium will change form in your hand from body heat (Mercury like)...Fun facts about Gallium....

Gallium is a chemical element with the symbol Ga and atomic number 31. Discovered by French chemist Paul-Émile Lecoq de Boisbaudran in 1875,[6] Gallium is in group 13 of the periodic table and is similar to the other metals of the group (aluminiumindium, and thallium).

Elemental gallium is a soft, silvery metal in standard temperature and pressure. In its liquid state, it becomes silvery white. If too much force is applied, the gallium may fracture conchoidally. Since its discovery in 1875, gallium has widely been used to make alloys with low melting points. It is also used in semiconductors, as a dopant in semiconductor substrates.

The melting point of gallium is used as a temperature reference point. Gallium alloys are used in thermometers as a non-toxic and environmentally friendly alternative to mercury, and can withstand higher temperatures than mercury. An even lower melting point of −19 °C (−2 °F), well below the freezing point of water, is claimed for the alloy galinstan (62–⁠95% gallium, 5–⁠22% indium, and 0–⁠16% tin by weight), but that may be the freezing point with the effect of supercooling.

Gallium does not occur as a free element in nature, but as gallium(III) compounds in trace amounts in zinc ores (such as sphalerite) and in bauxite. Elemental gallium is a liquid at temperatures greater than 29.76 °C (85.57 °F), and will melt in a person's hands at normal human body temperature of 37.0 °C (98.6 °F).

Gallium is predominantly used in electronicsGallium arsenide, the primary chemical compound of gallium in electronics, is used in microwave circuits, high-speed switching circuits, and infrared circuits. Semiconducting gallium nitride and indium gallium nitride produce blue and violet light-emitting diodes (LEDs) and diode lasers. Gallium is also used in the production of artificial gadolinium gallium garnet for jewelry. Gallium is considered a technology-critical element by the United States National Library of Medicine and Frontiers Media.[7][8]

Gallium has no known natural role in biology. Gallium(III) behaves in a similar manner to ferric salts in biological systems and has been used in some medical applications, including pharmaceuticals and radiopharmaceuticals. 

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